(R,R)-Ethylenebis-(4,5,6,7-tetrahydro-1- indenyl)-titanium(IV)-(R)-(1,1’Binaphthyl-2) 100mg
Produkt Artikelnummer: MC 1312
C40H36O2Ti
C40H36O2Ti
FW:
596.60
CAS:
143063-72-3
Beschreibung
Asymmetric Catalyst
for the hydrogenation of 1,1-disubsituted alkenes, trisubstituted olefins, enamines and imines. Synthesis of highly enantiomerically enriched cyclic amines, kinetic resolution of racemic disubstituted 1-Pyrrolines and enantioselective hydrosilylation of ketones. C. A. Willoughby, S. L. Buchwald, J. Am. Chem. Soc. 1992, 114, 7562; C. A. Willoughby, S. L. Buchwald, J. Org. Chem. 1993, 58, 7627; R. D. Broene, S. L. Buchwald, J. Am. Chem. Soc. 1993, 115, 12569; S. L. Buchwald et al., J. Am. Chem. Soc. 1994, 116, 5985, 9373 and 11667; C. A. Willoughby, S. L. Buchwald, J. Am. Chem. Soc. 1994, 116, 8952 and 11703